Tetra­methyl­ammonium dimethyl (phenyl­sulfonyl­amido)phosphate(1−)

نویسندگان

  • Elizaveta A. Trush
  • Oleg V. Shishkin
  • Victor A. Trush
  • Irina S. Konovalova
  • Tetyana Yu. Sliva
چکیده

The title compound, C(4)H(12)N(+)·C(8)H(11)NO(5)PS(-), was obtained from tetra-methyl-ammonium hydroxide and dimeth-yl(phenyl-sulfon-yl)amido-phosphate. The tetra-methyl-ammonium cation has a slightly distorted tetra-hedral configuration and the N-C bond lengths lie in the range 1.457 (3)-1.492 (3) Å. In the crystal, no classical hydrogen bonds are observed between the cation and the anion.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

One-dimensional Uranium(VI) Coordination Polymer Complex Containing Dimethyl and Trimethyl Phosphate Ligands: Synthesis, Spectroscopic Characterization, Thermal Analyses, and Crystal Structure

A new one-dimensional uranium(VI) coordination polymer, [UO2(μ-DMP)2(TMP)]n (1) (DMP is dimethyl phosphate and TMP is trimethyl phosphate), was prepared from the reaction of UO2(NO3)2.6H2O and TMP in in THF (THF is tetrahydrofuran) as a solvent. Suitable crystals of this complex for crystal structure determination were obtained by slow evaporation of the produced yellow solution at room tempera...

متن کامل

Tris(tetra­methyl­ammonium) tetra-μ2-sulfido-tetra­sulfidocopper(I)dimolyb­denum(VI) N,N-dimethyl­formamide solvate

The title compound, (C(4)H(12)N)(3)[CuMo(2)S(8)]·C(3)H(7)NO, was obtained from the self-assembly of tetra-thio-molybdate, tetra-methyl-ammonium nitrate and cuprous sulfide in dimethyl-formamide (DMF). The asymmetric unit contains three (NMe(4))(+) cations, one [Mo(2)S(8)Cu](3-) anion and one DMF solvent mol-ecule, and no obvious inter-actions are observed between these species. The trinuclear a...

متن کامل

Tetra­methyl­ammonium dihydrogen phosphate hemihydrate

In the crystal structure of the title compound, C(4)H(12)N(+)·H(2)PO(4) (-)·0.5H(2)O, the anions form an infinite hydrogen-bonded chain along the [10] direction. The anion chains are connected by water mol-ecules, which lie on crystallographic twofold rotation axes, through O-H⋯O hydrogen bonds. These hydrogen bonds are almost perpendicular to the other hydrogen bonds which create an assembled ...

متن کامل

Phosphate-guanosine interactions. A model for the involvement of guanine derivatives in autocatalytic reactions of ribonucleic acids.

Proton magnetic resonance was used to study the interactions between nucleosides and phosphate monoanion in dimethyl sulfoxide. Ribose was able to form two mutually exclusive 1:1 complexes involving either OH3' and OH5' or OH3' and OH2' as hydrogen bond donor groups. Deoxyribose could form only one of these complexes. A specific interaction of phosphate with the base moiety of nucleosides was o...

متن کامل

Phosphonate–Phosphinate Rearrangement

LiTMP metalated dimethyl N-Boc-phosphoramidates derived from 1-phenylethylamine and 1,2,3,4-tetrahydronaphthalen-1-ylamine highly selectively at the CH3O group to generate short-lived oxymethyllithiums. These isomerized to diastereomeric hydroxymethylphosphonamidates (phosphate–phosphonate rearrangement). However, s-BuLi converted the dimethyl N-Boc-phosphoramidate derived from 1-phenylethylami...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2012